The product specifications of condensate and NGL are described in the later chapters. DGA, despite a high heat of reaction, has a very high gas carrying capacity that usually produces very reasonable net energy requirements. Pipeline operators also require the product gas to be interchangeable and similar in properties with existing pipeline gas. Capacity. It'll be tough to turn this around by then without the cooperation of your compressor packaging vendor. However, advances in enhanced glycol dehydration processes, such as the DRIZO system, can solve the problem by production of a BTEX hydrocarbon liquid. All contents of the lawinsider.com excluding publicly sourced documents are Copyright © 2013-. Natural gas processing plants separate hydrocarbon gas liquids, nonhydrocarbon gases, and water from the natural gas before the natural gas is delivered into a mainline transmission system. However, complete removal of carbonyl sulfide by Sulfinol-D cannot be guaranteed. This is particularly useful in tail gas treating unit operation which requires maximum slippage of CO2, and moving the feed location to a lower location will help to concentrate H2S content in the acid gas to the Claus sulfur recovery unit. Don't you like to save the company money?”, “Your stupid cost-saving ideas will cost us more in downtime than you ever dreamed. Membrane and Twister processes are suitable for small gas plants and offshore installation where space is limited. The Department has determined that the burning of Pipeline Quality Natural Gas constitutes BACT for PM and SOX.III. The process selection can be quite straightforward. biogas have been removed to pipeline quality specifications prior to any blending with non­ renewable fuel streams. With Natural Gas, due to the nature of the product and the transportation mechanism, the quality of the delivered product is primarily determined by the pipeline. Canada's Enbridge operates … There are other considerations that may favor the use of molecular sieves. The solvent consists of an aqueous amine and sulfolane. The main difference is that while the conventional amine process employs a fairly diluted concentration of amine in water, removing the acid gas by chemical reaction, the Sulfinol system uses a mixture of highly concentrated amine and a physical solvent removing the acid gases by physical and chemical reactions. MDEA, with its some outstanding capabilities, resulting from its low heat of reaction, can be used in pressure swing plants for bulk acid gas removal. When the gas is high in heavy hydrocarbon contents, they must be removed to meet the heating value specification. It can also be accomplished with a TEG dehydration unit followed by propane chilling. Sulfur Oxides - Emissions of SO2 from natural gas-fired boilers are low because pipeline quality natural gas typically has sulfur levels of 2,000 grains per million cubic feet. “Sara, do you have an office where Dip and I can talk?”, “Sure, use the table in my office. Typical glycol dehydration process is suitable for meeting pipeline gas specification as low as −40°F and is more economical than molecular sieves technology. Additionally, pipeline natural gas must either be composed of at least 70 percent methane by volume or have a gross calorific value between 950 and 1100 Btu per standard cubic foot. The characteristics of various types of NGL products can be found in GPSA Engineering Data Book (2004). Gathering systems, primarily made up of small-diameter, low-pressure pipelines, move raw natural gas from the wellhead to a natural gas processing plant or to an interconnection with a larger mainline pipeline. Learn more about pipeline gas quality requirements here. Our pipelines offer a variety of customer oriented services. Sulfinol has a good affinity for most of the acid gases and has the ability to release these gases in the regenerator upon pressure reduction and heat application. However, continuous monitoring is not always feasible and offline (or laboratory) testing can be used in its place. Raw natural gas stream must be treated to comply with emissions regulations and pipeline gas specifications. “Well, I don't like it one damn bit,” said a gruff voice from the chairs along the back wall. The Sulfinol-D process uses DIPA, while Sulfinol-M uses MDEA. Use of Only Pipeline Quality Natural Gas as FuelNatural gas combustion when combined with good combustion practices generates less emissions than other fuels.Runtime Limitations Limiting the operation of a source where practical to eliminate excess emissions. The concentrations of the amine and the physical solvent vary with the type of feed gas in each application. Natural gas can be combusted for space or water heating, used in turbines to generate electricity, or used as a transportation fuel. Deep removal of carbon dioxide removal for liquefied natural gas plants is another application, as well as bulk carbon dioxide removal with flash regeneration of the solvent. The pipeline's north section has already delivered nearly 4 billion cbm of Russian natural gas to China, and once all three sections are up and running, the maximum annual gas supply can reach 38 billion cbm, supplying 400 million people along the route. Common Sulfinol mixtures are in the range of 40% amine (also called DIPA), 40% sulfolane (an organic solvent), and 20% water. Pipeline Quality Renewable Natural Gas. Pipeline Quality Natural Gas shall be exempt from this requirement (III.A.1.iii.) Propane and butane can be sold as liquefied petroleum gas (LPG). It will make the foundation less complicated and reduce the structural costs.”. Typical glycol dehydration process is suitable for meeting pipeline gas specification; as low as −40 °F and is more economical than molecular sieves technology. You'd better talk to Chet.”. Heating Value HV 36.0 to 41.3 MJ/m. Pipeline operators also require the product gas to be interchangeable and similar in properties with existing pipeline gas. DGA also has a good potential for absorbing COS and some mercaptans from gas and liquid streams, and, because of this, DGA has been used in both natural and refinery gas applications. The removed liquid hydrocarbons can typically command a higher value than natural gas for the same heating value. Frederick B. Typical pipeline gas specifications. The principal constituents are methane and carbon dioxide. The pipeline gas specification was incomplete, but Johnny Bent, the Project Engineer for the pipeline tie-in, had agreed to call a meeting to resolve the matter. Some wellhead natural gas is sufficiently dry and satisfies pipeline transportation standards without processing. Montauk's Role. The United States has 11 distinct natural gas pipeline corridors: five originate in the Southwest, four deliver natural gas from Canada, and two extend from the Rocky Mountain region. Table 3-1. A wide range of treating pressures and contaminant concentrations can be accommodated. Figure 7-20. The C2+ NGL, which is termed “Y-Grade” NGL, shall meet the specifications given in Table 1.2. Solid desiccant dehydrators are chosen for deep dehydration to meet a low water dew point for NGL recovery or LNG production. Sometimes a slight change on the product specifications may have significant impacts on the treatment and processing options, which will affect the cost and complexity of the gas plant. Note should be made that sometimes a slight change on the product specifications may have significant impacts on the processing options, which will affect the cost and complexity of the gas processing plant. The 9.20. Safety assurance is dependent on the quality of the work resulting from carrying out those procedures and practices. Typical Pipeline Gas Specifications. Based on the currently “accepted” operating conditions, MEA is usually not preferred for its high heat of reaction and lower acid gas carrying capacity per unit volume of solution. Table 1: Renewable Natural Gas – Pipeline Gas Quality Specifications . It's two doors down the hall to the left. The definitions of “natural gas” and “pipeline natural gas” in § 72.2 also limit the hydrogen sulfide (H 2S) content of these fuels to <1.0 gr/100 scf (for natural gas) and < 0.3 gr/100 scf (for pipeline natural gas). The Department has determined that the burning of Pipeline Quality Natural Gas constitutes BACT for PM and SOX.IV. “That's great,” said Arlo, his face beaming. The natural gas dehydration process is selected based on the water dew point requirements, as shown in Fig. 3. Hydrogen sulfide selectivity in Sulfinol-M is controlled by the relative reaction rate of the reaction of hydrogen sulfide with methyldiethanolamine as well as by the physical solubility of hydrogen sulfide and carbon dioxide in the solvent. “Let's take a break,” said Arlo. The gas transported to California gas utilities via the interstate pipelines, as well as some of the California-produced gas, is delivered into the PG&E and SoCalGas intrastate natural gas transmission pipelines systems (commonly referred to as California's "backbone" pipeline system). The specifications are to ensure gas qualities and provide a clean and safe fuel gas to the consumers. When producing a pipeline gas, the feed location can be lowered to minimize CO 2 absorption as the pipeline gas specification is only 2 mol% CO 2. The removed natural gas liquids (NGLs) can typically command a higher value than natural gas for the same heating value. For water dew pointing lower than −40 °F and down to −80 °F, the enhanced TEG dehydration process, such as DRIZO, is suitable. In such cases, at least some of those heavy components must be removed to meet the heating value specification. For water dew pointing lower than −40°F and down to −80°F, the enhanced TEG dehydration process, such as DRIZO, is suitable. When the sales gas reaches a local gas utility, it normally passes through a gate station to serve three purposes: (1) reducing the pressure in the line from transmission levels to distribution levels, (2) adding an odorant so that consumers can smell even small quantities of gas, and (3) measuring the flow rate of the gas to determine the amount delivered to the utility. I need it by October 28th.”, “OK, Arlo, but that's only two weeks. When the gas is high in heavy hydrocarbon content, it may exceed the maximum allowable British thermal unit (Btu) specification. Technology selection can be based on many criteria, including the makeup of the biogas as well as site and operating conditions. Sulfinol-M is used when a higher degree of hydrogen sulfide selectivity is needed. “Sara, I don't think we need to go any further with the design review until we get this nozzle issue resolved. The natural gas dehydration process is selected based on the water dew point requirements, as shown in Figure 7-20. Pipeline operators also require the product gas to be interchangeable and similar in properties with existing pipeline gas. The removed liquid can typically command a higher value than natural gas for the same heating value. Howe… Natural Gas (Pipeline Quality) SAFETY DATA SHEET Date of Preparation: June 13, 2017 Page 3 of 10 Deerfoot Consulting Inc. may vent and release flammable gas through pressure relief devices. When producing a pipeline gas, the feed location can be lowered to minimize CO2 absorption as the pipeline gas specification is only 2 mol% CO2. The total sulfur compounds in the treated gas can be reduced to ultra-low ppm levels, as required for refinery fuel and pipeline quality gases. The specifications ensure gas quality to provide a clean and safe fuel gas to consumers. William A. Poe, Saeid Mokhatab, in Modeling, Control, and Optimization of Natural Gas Processing Plants, 2017. Pipeline Quality Natural Gas means, for the purpose of calculating emissions under MRR, natural gas having a high heat value greater than 970 Btu/scf and equal to or less than 1,100 Btu/scf, and which is at least ninety percent (90%) methane by volume, and which is less than five percent (5%) carbon dioxide by volume. Sometimes a slight change in the product specifications may have significant impacts on the treatment and processing options, which will affect the cost and complexity of the gas plant. The need to ensure quality has led many natural gas utilities to create quality management programs. Ethane can be used as feedstock to petrochemical plants. The C5+ components can be exported to refineries as a blending stock for gasoline. It can also be accomplished with TEG dehydration unit followed by propane chilling. Continuous D1945 / D7164 Carbon Dioxide CO. 2. Value Unit Monitoring Frequency* Recommended Test . Pipeline Quality Natural Gas. When operating under suitable conditions, it is capable of removing twice as much acid gas as a 20% MEA solution. CLEANING BIOGAS TO PIPELINE QUALITY STANDARDS Several methods and technologies are available to condition and upgrade biogas into renewable natural gas (RNG) and remove constituents of concern. Ethane can be used as feedstock to petrochemical plants. This NAESB-compliant web site will allow you to select a pipeline group/pipeline from the menu bar on the left, and easily navigate to the section of this site that interests you by selecting the appropriate section from the expanded menu. Utility generators have a need to know the expected range of quality of the fuel being delivered to them Alireza Bahadori Ph.D., in Natural Gas Processing, 2014. That's over $1 million in lost gas sales right there. The Sulfinol-D process is primarily used in cases where selective removal of hydrogen sulfide is not of primary concern, but where partial removal of organic sulfur compounds (mercaptans, RSH, and carbon disulfide) is desired, typically in natural gas and refinery applications. An improved application is to selectively remove hydrogen sulfide, carbonyl sulfide, mercaptan derivatives, and other organic sulfur compounds for pipeline specification, while coabsorbing only part of the carbon dioxide. The actual chemical formulation is customized for each application. Note that in addition to the specified impurity levels for the contaminants, the specifications include the heating value of natural gas (950 -1150 Btu/scf) which depends on the composition, particularly the concentration of inert gases (e.g., N 2 and CO 2 ) and other diluents. that has been upgraded for use in place of fossil natural gas. The McCarty Road landfill is owned and operated by Republic Services and is one of the largest waste disposal facilities in Texas. Saeid Mokhatab, ... John Y. Mak, in Handbook of Natural Gas Transmission and Processing (Third Edition), 2015. Natural gas, consisting primarily of methane, has a number of advantages compared to liquid fuels such as gasoline and diesel fuel. Midcontinent Express Pipeline (MEP) is a 510-mile natural gas pipeline that originates near Bennington, Oklahoma and terminates at an interconnection with Transcontinental Gas Pipe Line near Butler, Alabama. The characteristics of various types of natural gas liquid (NGL) products can be found in the GPSA (2004) Engineering Data Book. It is important to recognize the definitions and specifications of the treated gas and product specifications. Would you have your people price the change to bottom nozzles so we can study our options? ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B9780128158173000010, URL: https://www.sciencedirect.com/science/article/pii/B9780128029619000012, URL: https://www.sciencedirect.com/science/article/pii/B9780128014998000031, URL: https://www.sciencedirect.com/science/article/pii/B9780128158173000046, URL: https://www.sciencedirect.com/science/article/pii/B9780750682794500064, URL: https://www.sciencedirect.com/science/article/pii/B9780128158173000071, URL: https://www.sciencedirect.com/science/article/pii/B9780128158173000095, URL: https://www.sciencedirect.com/science/article/pii/B9780128014998000079, URL: https://www.sciencedirect.com/science/article/pii/B9780080999715000106, URL: https://www.sciencedirect.com/science/article/pii/B9780128095706000084, Handbook of Natural Gas Transmission and Processing (Fourth Edition), After the raw gas has been processed to meet, Introduction to Natural Gas Processing Plants, Modeling, Control, and Optimization of Natural Gas Processing Plants, Raw natural gas stream must be treated to comply with emissions regulations and, Handbook of Natural Gas Transmission and Processing (Third Edition), Raw natural gas streams must be treated to comply with emissions, regulations, and, Learning Project Engineering on the Job: A Case Study, Natural Gas Dehydration and Mercaptans Removal, Not to exceed either 0.5 vol% of total stream or 1.5 vol% of ethane content, 1 wt% in total stream or 10 vol% in contained natural gasoline, 500 ppmv or 0.35 liquid volume % of ethane. Once biomethane gas to grid is accomplished, the biogas plant operator gains not only from a higher price for the energy than for electricity. Pollutant concentration monitor means that component of the continuous emission monitoring system that measures the concentration of a pollutant in a unit 's flue gas. Continuous D1945 / D7164 Wobbe Index WN 47.2 to 51.1 MJ/m. The EPA criteria for pipeline quality natural gas from [40CFR72.2] is as follows: "Pipeline natural gas means a naturally occurring fluid mixture of hydrocarbons (e.g., methane, ethane, or propane) produced in geological formations beneath the Earth's surface that maintains a gaseous state at standard atmospheric temperature and pressure under ordinary conditions, and which is provided by a supplier … Containers may explode when heated. We operate the landfill gas collection system and are the owner and operator of the gas processing facility. The Y-Grade liquids must be free from sand, dust, gums, gum-producing substances, oil, glycol, inhibitor, amine, caustics, chlorides, oxygenates, heavy metals, and any other contaminants or additive to the product used to enhance the ability to meet specifications. Molecular sieves are selective and do not appreciably adsorb BTEX components hence avoiding the emissions problem in conventional TEG dehydration unit. The mercaptans are concentrated in the regeneration gas, and can be selectively removed using a physical solvent process, such as the DEPG process. It is important to recognize the definitions and specifications of the treated gas and product specifications. Pipeline Quality Natural Gas: during natural gas operations, combust only pipeline quality natural gas. After the raw gas has been processed to meet pipeline gas specifications, the marketable (sales) gas is transported through pipelines to industrial and residential consumers or to underground storage facilities for later delivery to these consumers as demand dictates. That's your problem.” Dip got up from the table and left the building. gas was converted into the 18.9 Tcf of dry natural gas that was put into the pipeline system. “Arlo, I don't care about your schedule. A TEG dehydration unit is lower in CAPEX and OPEX than the molecular sieve unit, especially for offshore installation where plot space is limited. We use cookies to help provide and enhance our service and tailor content and ads. When the gas is high in heavy hydrocarbon contents, they must be removed to meet the heating value specification. Molecular sieves can be designed to remove mercaptans to meet the sulfur specifications. Renewable natural gas (RNG)* is a term used to describe biogasbiogasGas resulting from the decomposition of organic matter under anaerobic conditions. Molecular sieves can be designed to remove mercaptans to meet the sulfur specifications. Figure 9.20. The process is used for the removal of hydrogen sulfide, carbonyl sulfide, mercaptan derivatives, other organic sulfur compounds and all or part of the carbon dioxide from natural, synthetic, and refinery gases. A number of compressor stations (containing one or more compressor units) are located along the pipeline system to maintain the pipeline pressure and overcome the pressure drop in the pipeline. Background Natural gas processing begins at the wellhead (Figure 1). Gas dehydration technology selection. RNG can be used where it is produced for purposes such as generating electricity or fueling vehicles, or it can be injected into the utility pipeline and transported to an end user. … The Sulfinol mixed solvent consists of a chemical-reacting alkanolamine, water, and physical solvent sulfolane (tetra-hydrothiophene dioxide). The C5+ components fraction (condensate) can be exported to refineries as a blending stock for gasoline. The process is in many respects identical to the familiar amine method and its equipment components similar to those found in amine units. We'll adjourn until you return.”, “What do you mean you don't like it, Dip? From the gate station, sales gas then moves into distribution lines to supply gas to the end users/customers. MDEA is currently best known for its ability to preferentially absorb H2S. Walter replaced Edgar beside the projector and began covering the compressor design and the site layout drawings. The specifications are to ensure gas qualities and provide a clean and safe fuel gas to the consumers. Copyright © 2020 Elsevier B.V. or its licensors or contributors. Typical pipeline gas specifications are shown in Table 1.1. Nearly three quarters of Colorado households use natural gas to heat their homes. Propane and butane can be sold as liquefied petroleum gas (LPG). Propane and butane can be sold as liquefied petroleum gas (LPG). OVID, Mich. (AP) — Michigan’s Public Service Commission has approved Consumers Energy’s application to build a wider natural gas pipeline. The mercaptan components can then be converted to sulfur in a Claus sulfur recovery unit to eliminate sulfur emissions. Sara thought Arlo looked like he had just come from a traffic accident. The new Mid-Michigan Pipeline … The mixed solvents allow for better solvent loadings at high acid gas partial pressures and higher solubility of carbonyl sulfide and organic sulfur compounds than straight aqueous amines. This produces renewable natural gas, or RNG, which can be used interchangeably with traditional natural gas. provided Permittee receives and maintains quarterly records of the vendor’s analysis, and the data is of sufficient quality to yield further analysis as required above. Table 12.4 gives the natural gas specifications that need to be satisfied for pipeline transportation. The separated NGL are called natural gas plant liquids (NGPL), and the processed natural gas is called dry, consumer-grade, or pipeline quality natural gas. Even routine maintenance of the compressor with top nozzles will take two and a half days to remove, replace, and test that high-pressure gas piping. Raw natural gas stream must be treated to comply with emissions regulations and pipeline gas specifications. Membrane and Twister processes are suitable for small gas plants and offshore installation where space is limited. Typical pipeline gas specifications are shown in Table 4.1. Y-grade NGL specifications (Mokhatab et al., 2015). Section 10.8 treats issues related to natural gas storage: capacity Multiple lean amine feed points can be installed in the absorber to provide the flexibility for selective CO2 removal. If dehydration is required only to meet the pipeline specification of 4–7 lb/MMscf, any of the above-mentioned processes can be applicable. Many process factors should be considered when selecting an amine for a sweetening application as outlined here: The initial selection should be based on the pressure and acid gas content of the sour gas as well as the purity specification for the product gas.

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